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Gasification Archive for June 2002
87 messages, last added Tue Nov 26 17:18:20 2002

[Date Index][Thread Index]

Re: GAS-L: NOx and gasifiers



On Wed, 26 Jun 2002 13:54:35 +0530, 
Prof P P Parikh <parikh@me.iitb.ac.in> wrote in message 
<Pine.GSO.4.21.0206261350510.17335-100000@epsilon.me.iitb.ac.in>:

> Nox in producer gas is a myth. Lower temperatures and oxugen
> defficiency will not make this happen. Yes, nox in engine exhaust is 
> a good possibility as with any other fuel. I will look for data and
> write back. Shashikanth did measure NOX in SIPGE.
> Mrs Parikh

..your findings are in agreement with Mikko Hupa's work:
Kapitel 2.3 Kväveoxiderna. [Chapter 2.3 (the) Nitrogenoxides.]
Inverkan av vatten och väte i förbränningsprocessen 
[Effect of water and hydrogen in (the) combustion process], 
by Docent Mikko Hupa, Åbo Akademi, Finland, source book title: 
Vattnets roll i förbränningen [Impact of water in combustion], 
IVA Rapport 324, 27 May 1986, Isbn 91 7082 417 7

..essence of his theorem:  NOx, NitrogenOxides
Fuel containing chemically bound Nitrogen decomposes 
through cyanide, HCN to:

...either:
CxHyNz + heat ---> 2 HCN + 3 O2 --->  H2O + 2 CO2 + 2 NO
(combustion in oxidizing process environment, NOX is formed)

...or:
CxHyNz + heat ---> 2 HCN + O2---> H2 + 2 CO +  N2
(thermochemical gasification in reducing process environment, 
No NOX, N2 is formed instead.)

..myself, I just translated and used some of it, and some more.
(And IIIIIIIII did it myyyyyyyyyyyyyy waaaaaaaaaaaaaaaaaaaay.  ;-)
http://www.crest.org/discussion/gasification/199903/msg00055.html
on http://www.ivar.rl.no/IDybden/avlop/analyse.biopellets.cfm 
Translate from norwegian: http://www.tranexp.com/InterTran.cgi )

-- 
..med vennlig hilsen = with Kind Regards from Arnt... ;-)
...with a number of polar bear hunters in his ancestry...
  Scenarios always come in sets of three: 
  best case, worst case, and just in case.


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