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Introduction Applications Reforming and Storage
Chapter 1 - Introduction

Fuel cells are electro-chemical devices that operate at a high level of efficiency with little noise or air pollution. There are many potential applications for fuel cells, including electricity generation in stationary applications and provision of motor force for a new generation of transportation vehicles.

All fuel cells operate on the same principle—they convert chemical energy directly into electricity and heat, rather than oxidize (burn) a fuel. In most, but not all fuel cells, the source of the fuel’s chemical energy is hydrogen. In some cases, the fuel may need to be processed, or “reformed,” before it can be used in the fuel cell.

An input fuel is catalytically reacted (electrons removed from the fuel elements) in the fuel cell to create an electric current. Fuel cells consist of an electrolyte material that is sandwiched in between two thin electrodes (porous anode and cathode). The input fuel passes over the anode and oxygen passes over the cathode where it catalytically splits into ions and electrons. The electrons go through an external circuit to serve an electric load while the ions move through the electrolyte toward the oppositely charged electrode. At the electrode, ions combine to create by-products, primarily water and CO2. Depending on the input fuel and electrolyte, different chemical reactions will occur.


Conceptual diagram of a fuel cell. Hydrogen and oxygen are combined electrochemically to produce energy, with water and useful heat as the only byproducts.

Source: Fuel Cells 2000 and the U.S. Department of Energy.